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NH4HS(s) ⇌ NH3(g) + H2S(g) Kp = 0.108 at 25℃

by 영원파란 2022. 12. 8.

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NH4HS(s) ⇌ NH3(g) + H2S(g) Kp = 0.108 at 25℃

 

 

Solid ammonium hydrogen sulfide, NH4HS,

dissociates appreciably even at room temperature

forming ammonia, NH3, and hydrogen sulfide, H2S, gases.

What is the total pressure at equilibrium

if solid NH4HS is placed in an evacuated container

and allowed to reach equilibrium?

Kp = 0.108 at 25℃.

 

---------------------------------------------------

 

ICE 도표를 작성하면,

 

 

 

 

NH4HS(s) ⇌ NH3(g) + H2S(g)

평형에서, ...... x ............ x

 

Kp = (P_NH3) (P_H2S) = (x) (x)

 

 

 

x^2 = 0.108

 

x = (0.108)^(1/2) = 0.329 atm

 

 

 

P_total = P_NH3 + P_H2S

= 0.329 + 0.329 = 0.658 atm

 

 

 

답: 0.658 atm

 

 

 

 

[ 관련 예제 https://ywpop.tistory.com/22792 ]

NH4HS total pressure 0.658 atm 25℃ free energy

 

[ 관련 예제 https://ywpop.tistory.com/22430 ]

295 K 0.265 atm Kc NH4HS(s) ⇌ NH3(g) + H2S(g)

 

 

 

[키워드] NH4HS(s) ⇌ NH3(g) + H2S(g) 기준문서

 

 

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